Bandlist 71 71

Absorption band list of CH4 in natural solid CH4 (phase I)

Title
Absorption band list of CH4 in natural solid CH4 (phase I)
Band list reference
Schmitt, Bernard and The SSHADE Band List Committee (2021): Absorption band list of CH4 in natural solid CH4 (phase I). Version 1. SSHADE (OSUG Data Center). Dataset/Band list Data. https://doi.org/10.26302/SSHADE/BANDLIST_ABS_CH4_CH4-I
Publication(s)
Type
absorption
Description
FIR-MIR-NIR-Vis absorption band list of the isotopes of CH4 in natural solid CH4 (phase I) at 30 and 90 K
Number of bands
71
Comments
The ν1 and ν2 modes are inactive in the IR. The ν3 mode is affected by free rotation of CH4 in phase I.
Position (cm-1) Width (cm-1) Peak intensity (cm-1) Relative intensity Strength Transition mode Mode type(s) Bond Specie(s) Degeneracy Resonances
160 ± 10 160 ± 10 130 ± 15 1 ± 0.1 1.25e-04 vw
νR
hindered rotation
12CH4
other
1299 ± 0.5 1299 ± 0.5 8000 ± 300 1 vs
ν4
deformation
12C-1H
12CH4
triple
2598 ± 2 2598 ± 2 24.8 ± 0.5 0.0031 m
4
deformation
12C-1H
12CH4

2819 ± 2 2819 ± 2 133 ± 2 0.016625 s
ν24
deformation
deformation
12C-1H
12C-1H
12CH4

3009 ± 2 3009 ± 2 5300 ± 200 0.6625 vs
ν3
ν3 + nνR
stretching asym.
stretching asym.
hindered rotation
12C-1H
12C-1H
12CH4
12CH4
other
other

3846 ± 1 3846 ± 1 48.4 ± 1 0.00605 m
4
deformation
12C-1H
12CH4

3897 ± 4 3897 ± 4 3.39 ± 0.05 4.237e-04 w
4
deformation
12C-1H
12CH4

4116 ± 1 4116 ± 1 9.59 ± 0.2 0.0012 w
ν2+2ν4
deformation
deformation
12C-1H
12C-1H
12CH4

4203 ± 1 4203 ± 1 515 ± 10 0.064375 s
ν14
stretching sym.
deformation
12C-1H
12C-1H
12CH4

4304 ± 1 4304 ± 1 267 ± 5 0.033375 s
ν34
stretching asym.
deformation
12C-1H
12C-1H
12CH4

4530 ± 1 4530 ± 1 41.3 ± 1 0.00516 m
ν23
deformation
stretching asym.
12C-1H
12C-1H
12CH4

5114 ± 1 5114 ± 1 0.19 ± 0.004 2.375e-05 vw
4
deformation
12C-1H
12CH4

5162 ± 1 5162 ± 1 0.335 ± 0.007 4.188e-05 vw
4
deformation
12C-1H
12CH4

5384 ± 1 5384 ± 1 1.43 ± 0.03 1.788e-04 w
ν2+3ν4
deformation
deformation
12C-1H
12C-1H
12CH4

5507 ± 1 5507 ± 1 0.305 ± 0.02 3.812e-05 vw
unknown
unknown
12CH4

5566 ± 1 5566 ± 1 11.6 ± 0.2 0.00145 w
ν3+2ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

5596 ± 1 5596 ± 1 5.7 ± 0.1 7.125e-04 w
2+2ν4
deformation
deformation
12C-1H
12C-1H
12CH4


5800 ± 1 5800 ± 1 14.8 ± 0.3 0.00185 m
ν234
deformation
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

5848 ± 5 5848 ± 5 1.85 ± 0.15 2.313e-04 w
1
stretching sym.
12C-1H
12CH4

5919 ± 1 5919 ± 1 2.54 ± 0.04 3.175e-04 w
ν13
stretching sym.
stretching asym.
12C-1H
12C-1H
12CH4

5990 ± 1 5990 ± 1 27 ± 0.5 0.00337 m
3
stretching asym.
12C-1H
12CH4

6034 ± 2 6034 ± 2 7.59 ± 0.15 9.488e-04 w
23
deformation
stretching asym.
12C-1H
12C-1H
12CH4

6616 ± 2 6616 ± 2 0.03 ± 5.0e-04 3.75e-06 vvw
ν2+4ν4
deformation
deformation
12C-1H
12C-1H
12CH4

6735 ± 1 6735 ± 1 0.649 ± 0.015 8.112e-05 vw
ν1+3ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

6858 ± 3 6858 ± 3 0.259 ± 0.005 3.238e-05 vw
ν3+3ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

6882 ± 3 6882 ± 3 0.286 ± 0.005 3.575e-05 vw
2+3ν4
deformation
deformation
12C-1H
12C-1H
12CH4

6999 ± 2 6999 ± 2 0.312 ± 0.005 3.9e-05 vw
ν12+2ν4
stretching sym.
deformation
deformation
12C-1H
12C-1H
12C-1H
12CH4

7066 ± 2 7066 ± 2 2.83 ± 0.05 3.538e-04 w
14
stretching sym.
deformation
12C-1H
12C-1H
12CH4

7084 ± 2 7084 ± 2 2.88 ± 0.05 3.6e-04 w
ν23+2ν4
deformation
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

7130 ± 2 7130 ± 2 3.71 ± 0.07 4.638e-04 w
ν134
stretching sym.
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

7195 ± 3 7195 ± 3 1.15 ± 0.02 1.437e-04 w
ν1+2ν24
stretching sym.
deformation
deformation
12C-1H
12C-1H
12C-1H
12CH4

7233 ± 2 7233 ± 2 1.83 ± 0.04 2.288e-04 w
2+2ν4
deformation
deformation
12C-1H
12C-1H
12CH4

7279 ± 3 7279 ± 3 2.28 ± 0.05 2.85e-04 w
34
stretching asym.
deformation
12C-1H
12C-1H
12CH4

7303 ± 3 7303 ± 3 2.61 ± 0.05 3.262e-04 w
234
deformation
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

7351 ± 3 7351 ± 3 2.77 ± 0.05 3.462e-04 w
ν123
stretching sym.
deformation
stretching asym.
12C-1H
12C-1H
12C-1H
12CH4

7488 ± 1 7488 ± 1 5.23 ± 0.1 6.538e-04 w
ν2+2ν3
deformation
stretching asym.
12C-1H
12C-1H
12CH4

8045 ± 1 8045 ± 1 0.0463 ± 0.001 5.788e-06 vvw
ν1+4ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

8087 ± 1 8087 ± 1 0.0494 ± 0.001 6.175e-06 vvw
ν3+4ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

8257 ± 2 8257 ± 2 0.0885 ± 0.002 1.106e-05 vvw
ν12+3ν4
stretching sym.
deformation
deformation
12C-1H
12C-1H
12C-1H
12CH4

8307 ± 1 8307 ± 1 0.36 ± 0.007 4.5e-05 vw
ν23+3ν4
deformation
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

8389 ± 1 8389 ± 1 0.887 ± 0.02 1.109e-04 vw
1+2ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

8409 ± 1 8409 ± 1 0.829 ± 0.02 1.036e-04 vw
ν13+2ν4
stretching sym.
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

8542 ± 5 8542 ± 5 1.39 ± 0.03 1.737e-04 w
34
stretching asym.
deformation
12C-1H
12C-1H
12CH4

8587 ± 1 8587 ± 1 4.77 ± 0.1 5.962e-04 w
124
stretching sym.
deformation
deformation
12C-1H
12C-1H
12C-1H
12CH4

8630 ± 3 8630 ± 3 0.8 ± 0.2 1.0e-04 vw
unknown
unknown
12CH4

8758 ± 2 8758 ± 2 1.09 ± 0.02 1.363e-04 vw
13
stretching sym.
stretching asym.
12C-1H
12C-1H
12CH4

8782 ± 1 8782 ± 1 2.59 ± 0.05 3.237e-04 w
ν2+2ν34
deformation
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

8881 ± 1 8881 ± 1 0.955 ± 0.02 1.194e-04 vw
ν1+2ν3
stretching sym.
stretching asym.
12C-1H
12C-1H
12CH4

9021 ± 2 9021 ± 2 0.109 ± 0.002 1.363e-05 vw
3
stretching asym.
12C-1H
12CH4

9688 ± 3 9688 ± 3 0.023 ± 0.001 2.875e-06 vvw
unknown
unknown
12CH4

9734 ± 1 9734 ± 1 0.0317 ± 6.0e-04 3.962e-06 vvw
ν13+3ν4
stretching sym.
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

9855 ± 2 9855 ± 2 0.206 ± 0.004 2.575e-05 vw
3+3ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

9980 ± 1 9980 ± 1 0.143 ± 0.003 1.788e-05 w
14
stretching sym.
deformation
12C-1H
12C-1H
12CH4

10014 ± 4 10014 ± 4 0.0836 ± 0.0015 1.045e-05 vvw
134
stretching sym.
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

10081 ± 2 10081 ± 2 0.252 ± 0.005 3.15e-05 vw
ν1+2ν34
stretching sym.
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

10244 ± 4 10244 ± 4 0.05 ± 0.01 6.25e-06 vvw
unknown
unknown
12CH4

10270 ± 2 10270 ± 2 0.114 ± 0.002 1.425e-05 vvw
34
stretching asym.
deformation
12C-1H
12C-1H
12CH4

10466 ± 4 10466 ± 4 0.00305 ± 1.5e-04 3.813e-07 ew
ν2+3ν3
deformation
stretching asym.
12C-1H
12C-1H
12CH4

10514 ± 3 10514 ± 3 0.005 ± 2.5e-04 6.25e-07 ew
2+2ν3
deformation
stretching asym.
12C-1H
12C-1H
12CH4

10888 ± 6 10888 ± 6 0.0077 ± 5.0e-04 9.625e-07 ew
3+2ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

11088 ± 1 11088 ± 1 0.182 ± 0.004 2.275e-05 vw
3+4ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

11151 ± 2 11151 ± 2 0.167 ± 0.004 2.087e-05 vw
1+2ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

11240 ± 1 11240 ± 1 0.549 ± 0.01 6.863e-05 vw
13+2ν4
stretching sym.
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

11506 ± 2 11506 ± 2 0.0748 ± 0.0015 9.35e-06 vvw
3+2ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

11584 ± 2 11584 ± 2 0.036 ± 0.001 4.5e-06 vvw
unknown
unknown
12CH4

11846 ± 3 11846 ± 3 0.0111 ± 3.0e-04 1.388e-06 ew
ν1+3ν3
stretching sym.
stretching asym.
12C-1H
12C-1H
12CH4

11884 ± 3 11884 ± 3 0.011 ± 3.0e-04 1.375e-06 ew
3
stretching asym.
12C-1H
12CH4

12511 ± 4 12511 ± 4 0.0145 ± 3.0e-04 1.813e-06 vvw
1+3ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

12719 ± 3 12719 ± 3 0.0135 ± 2.5e-04 1.687e-06 vvw
3+3ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

13706 ± 3 13706 ± 3 0.0525 ± 0.001 6.563e-06 vvw
1+4ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

13835 ± 4 13835 ± 4 0.022 ± 0.001 2.75e-06 vvw
1+4ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

Spectral range type(s)
NIR, MIR, FIR
Spectral range(s)
100 - 13900 cm-1
Reference position infrared
1300 cm-1

Versions

Release date
2021-10-01 12:55:13 UTC+0000
Version (Date)
#1 (2021-10-01 12:55:13 UTC+0000, Updated: 2021-10-01 12:55:13 UTC+0000)
Newer/Last version(s)
History
Date Mode Version Status Comments
2021-10-01 08:14:49 UTC+0000 first import #1
Analysis
currently limited to the data and compilation in Quirico et al. (1997a) and Grundy et al. (2002) papers
Quality flag
4
Validation date
2021-08-11
Validators