Bandlist 5 5

Raman band list of CO2 in solid CO2 (phase I)

Title
Raman band list of CO2 in solid CO2 (phase I)
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Data
Individual bands
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Representation
Simple
Gaussian
Peaks
Data
Unit:  Range: Valid spectral range(s): 60.0 - 1400.0 cm-1
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Band list reference
Schmitt, Bernard and The SSHADE Band List Committee (2021): Raman band list of CO2 in solid CO2 (phase I). Version 1. SSHADE (OSUG Data Center). Dataset/Band list Data. https://doi.org/10.26302/SSHADE/BANDLIST_RAMAN_CO2_CO2-I
Publication(s)
Type
Raman scattering
Description
FIR-MIR Raman band list of the isotopes of CO2 in solid CO2 (phase I)
Number of bands
5
Other bandlists of this constituent
Constituent and primary specie
Constituent
CO2 - phase I
Primary specie
CO2 (Carbon dioxide)
Bands
Position (cm-1) Width (cm-1) Peak intensity (cm-1) Relative intensity Strength Transition mode Mode type(s) Bond Specie(s) Degeneracy Resonances
74 ± 1 74 ± 1 1.5 ± 1.3 1 vs
νL (Eg )
libration
12C16O2
double
91.5 ± 1.8 91.5 ± 1.8 2 ± 1.7 0.24 vs
νL (Tg ⁻)
libration
12C16O2
triple
132 ± 2.5 132 ± 2.5 4 ± 2 0.1 s
νL (Tg ⁺)
libration
12C16O2
triple
1277 ± 1.5 1277 ± 1.5 1.8 ± 0.2 0.2 s
2ν2
bending
12C16O2
12C16O2

1385 ± 1.5 1385 ± 1.5 1.7 ± 0.2 0.1 s
ν1
stretching
≥ 12C-16O-
12C16O2

Spectral range type(s)
FIR, MIR
Spectral range(s)
60 - 1400 cm-1
Reference position Raman
1385 cm-1

Versions

Release date
2021-10-01 12:56:51 UTC+0000
Version (Date)
#1 (2021-10-01 12:56:51 UTC+0000, Updated: 2024-12-23 20:11:35 UTC+0000)
History
Date Mode Version Status Comments
2021-10-01 07:31:44 UTC+0000 first import #1 valid version
Analysis
Compilation and review of all the available publications on Raman spectra of solid CO2-I from mid-IR to far-IR: Cahill and Leroi (1969), Ranson et al. (1988), Lowen et al. (1989), Bini et al. (1992)
Quality flag
4
Validation date
2021-09-07
Validators