- Type
- absorption
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| ν3 | stretching asym. | 13C16O2 | CO2 | ≥ 13C-16O- | no |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 2282.4 ± 0.4 | - | - | symmetric | 3200 ± 100 | vs | s | 70.0 |
- Label
- ν3
- Category
- fundamental vibration
- Method
- comparison with gas phase
Evaluation
- Level
- fully assigned
- Evaluation
- validated
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no |
- Primary specie
- 13C16O2
- Label (type)
- ν3 (stretching asym.) Bond: ≥ 13C-16O-
Vibration modes
- Temperature
- 70.0 ± 10.0 K
Temperature
- Method #1
- spectrum measurement
- Overlap
- isolated
- Peak
- 2282.4 ± 0.4 cm-1 (various)
- Evaluation
- validated
- Quality
- A
- Shape
- symmetric
- Evaluation
- undefined
- Quality
- undefined
- Method
- peak intensity
- Absorption coefficient
- 3200 ± 100 cm-1
- Strength
- very strong (vs)
- Evaluation
- validated
- Quality
- B
- Method
- extrapolated
- Strength
- strong (s)
- Evaluation
- undefined
- Quality
- undefined
- Publications
- SSHADE spectra
-
- Quirico, Eric; Schmitt, Bernard (2006): Near-IR optical constants spectrum of crystalline CO2 ice at 179 K completed with 28K data. Version 1. SSHADE/GhoSST (OSUG Data Center). Dataset/Spectral Data.
- Trotta, Frederic; Schmitt, Bernard (1996): MIR-FIR optical constants spectrum of crystalline CO2 ice at 15 K. Version 1. SSHADE/GhoSST (OSUG Data Center). Dataset/Spectral Data.