Bandlist
Absorption band list of CO2 in solid CO2 (phase I)
Sub-Bandlist
Combination and overtone vibration modes
Sub-Bandlist
12C16O2 - 1800- 2100 cm-1 group
Band
1915.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
1936.2 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
2023.2 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
2028.3 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
2041.7 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
2065.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Sub-Bandlist
12C16O2 - 2400- 3100 cm-1 group
Band
2459.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
2607.8 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
2660.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
2721.2 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
2740.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
2767.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
2840.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
2937.6 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3001.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3006.2 cm-1: unknown of 12C16O2 in CO2 - phase I
Sub-Bandlist
12C16O2 - 3100- 3900 cm-1 group
Band
3155.1 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3187.9 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3304.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3319.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3324.1 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3443.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3478.7 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3481.4 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3486.7 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3513.8 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3562.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3580.7 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3599.3 cm-1: 2ν2+ν3 of 12C16O2 in CO2 - phase I
Band
3632.2 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3667.3 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3686.3 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3707.8 cm-1: ν1+ν3 of 12C16O2 in CO2 - phase I
Band
3778.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3803.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
3822.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Sub-Bandlist
12C16O2 - 4200- 5400 cm-1 group
Band
4255.3 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4362.7 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4588.6 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4634.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4697.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4713.3 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4722.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4774.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4790.8 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4830.5 cm-1: 4ν2+ν3 of 12C16O2 in CO2 - phase I
Band
4877.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4897.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4932.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4946.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4957.8 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4971.0 cm-1: ν1+ν2+ν3 of 12C16O2 in CO2 - phase I
Band
4985.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
4998.7 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
5026.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
5038.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
5053.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
5065.3 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
5086.7 cm-1: 2ν1+ν3 of 12C16O2 in CO2 - phase I
Band
5117.1 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
5139.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
5181.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
5303.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
5322.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
5324.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
5337.7 cm-1: unknown of 12C16O2 in CO2 - phase I
Sub-Bandlist
12C16O2 - 6000- 7100 cm-1 group
Band
6044.0 cm-1: 6ν2+ν3 of 12C16O2 in CO2 - phase I
Band
6099.8 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6112.2 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6213.5 cm-1: ν1+4ν2+ν3 of 12C16O2 in CO2 - phase I
Band
6236.3 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6241.7 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6272.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6286.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6339.0 cm-1: 2ν1+2ν2+ν3 of 12C16O2 in CO2 - phase I
Band
6351.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6482.0 cm-1: 3ν1+ν3 of 12C16O2 in CO2 - phase I
Band
6518.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6663.6 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6669.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6777.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6920.1 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6935.7 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6950.2 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
6969.2 cm-1: 3ν3 of 12C16O2 in CO2 - phase I
Band
6997.9 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
7015.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Sub-Bandlist
12C16O2 - 7400- 8400 cm-1 group
Band
7436.9 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
7584.8 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
7717.7 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
7892.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
7966.4 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
8087.6 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
8180.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
8265.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
8289.5 cm-1: unknown of 12C16O2 in CO2 - phase I
Band
8360.0 cm-1: unknown of 12C16O2 in CO2 - phase I
Sub-Bandlist
Electronic transition modes
Band
54300.0 cm-1: A-X of 12C16O2 in CO2 - phase I
Band
70350.0 cm-1: Δu ← 1Σ⁺g of 12C16O2 in CO2 - phase I
Band
79250.0 cm-1: 1Πg ← 1Σ⁺g of 12C16O2 in CO2 - phase I
Band
86580.0 cm-1: 1Σ⁺u ← 1Σ⁺g of 12C16O2 in CO2 - phase I
Band
88200.0 cm-1: D-X of 12C16O2 in CO2 - phase I
Band
92000.0 cm-1: E-X of 12C16O2 in CO2 - phase I
- Type
- absorption
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| Δu ← 1Σ⁺g | intervalence charge transfer | 12C16O2 | CO2 | unknown | unknown |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 70350 ± 200 | 9400 ± 100 | undefined | 11000 | 0.018 | s | 0.041 | vs | 9.0 |
- Label
- Δu ← 1Σ⁺g
- Category
- electronic transition
- Method
- comparison with fundamental band
Evaluation
- Level
- fully assigned
- Evaluation
- undefined
- Comments
- unassigned by Lu 2008
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | unknown | unknown |
- Primary specie
- 12C16O2
- Label (type)
- Δu ← 1Σ⁺g (intervalence charge transfer)
Electronic modes
- Texture
- thin film
- Temperature
- 9.0 ± 2.0 K
- Formation temperature
- 9.0 K
Temperature
- Method #1
- spectrum measurement
- Overlap
- slightly blended
- Center
- 70350 ± 200 cm-1 (fit center)
- Evaluation
- validated
- Quality
- E
- FWHM
- 9400 ± 100 cm-1 (fit fwhm)
- Shape
- undefined
- Evaluation
- validated
- Quality
- E
- Method
- fit intensity
- Absorption coefficient
- 11000 cm-1
- Relative intensity
- 0.018 ± 0.001
- Strength
- strong (s)
- Evaluation
- validated
- Quality
- C
- Method
- band integrated intensity
- Relative intensity
- 0.041 ± 0.001
- Strength
- very strong (vs)
- Evaluation
- validated
- Quality
- B