- Type
- absorption
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| 2νL | libration | H2 16O | H2O | no | no |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1630 ± 7 | - | - | undefined | s | 20.0 | |||||||
| 1630 ± 20 | - | - | undefined | s | 100.0 | |||||||
| 1630 ± 20 | - | - | undefined | 935 ± 50 | 0.033 | s | 140.0 |
- Label
- 2νL
- Category
- overtone rotation
Evaluation
- Level
- fully assigned
- Evaluation
- validated
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no | no |
- Primary specie
- H2 16O
- Label (type)
- 2νL (libration)
Rotation modes
- Temperature
- 20.0 ± 10.0 K
- Formation temperature
- 273.0 K
- Temperature max
- 273.0 K
Temperature
- Method #1
- spectrum measurement
- Overlap
- strongly blended
- Peak
- 1630 ± 7 cm-1 (peak)
- Evaluation
- undefined
- Quality
- D
- Shape
- undefined
- Evaluation
- undefined
- Method
- extrapolated
- Strength
- strong (s)
- Evaluation
- undefined
- Temperature
- 100.0 ± 10.0 K
Temperature
- Method #1
- spectrum measurement
- Overlap
- strongly blended
- Peak
- 1630 ± 20 cm-1 (peak)
- Evaluation
- undefined
- Quality
- E
- Shape
- undefined
- Evaluation
- undefined
- Method
- extrapolated
- Strength
- strong (s)
- Evaluation
- undefined
- Temperature
- 140.0 ± 10.0 K
Temperature
- Method #1
- spectrum measurement
- Overlap
- strongly blended
- Peak
- 1630 ± 20 cm-1 (peak)
- Evaluation
- undefined
- Quality
- E
- Shape
- undefined
- Evaluation
- undefined
- Method
- peak intensity
- Absorption coefficient
- 935 ± 50 cm-1
- Relative intensity
- 0.033 ± 0.002
- Strength
- strong (s)
- Evaluation
- undefined
- Quality
- C
- Publications
-
- Trotta, 1996, 1 - 220
- Hardin and Harvey, 1973, Spectrochim. Acta, Part A, 29, 1139 - 1151
- Mastrapa et al., 2009, Astrophys. J., 701, 1347 - 1356
- Bertie and Whalley, 1964, J. Chem. Phys., 40, 1637 - 1645
- Bertie et al., 1969, J. Chem. Phys., 50, 4501 - 4520
- Hagen et al., 1981, Chem. Phys., 56, 367 - 379
- Data publication experiments
- Comments
- Ockman thesis 1957