- Type
- absorption
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| 2ν1 in-phase | stretching sym. | H2 16O | H2O | -16O-1H | no | no | unknown | ||
| ν1+2ν2 | combination vibration | H2 16O | H2O |
-16O-1H H2 16O |
no | no | unknown |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 6021 ± 1 | 6037 ± 1 | 87 | symmetric | 30 ± 1.5 | m | 10.0 | ||||||
| 6048 ± 1 | 6059 ± 1 | 99 | symmetric | 15.3 ± 1 | w | 100.0 | ||||||
| 6073 ± 1 | 6071 ± 1 | 106 | broad shoulder | 8.1 ± 0.5 | 3.3e-04 | w | 140.0 | |||||
| 6117 ± 1 | 130 | undefined | 0.1 ± 0.1 | ew | 270.0 |
- Label
- ν1+2ν2
- Category
- combination vibration
Evaluation
- Level
- uncertain assignment
- Evaluation
- uncertain
- Comments
- Ockman 1957
- Contribution level
- unknown
- Contribution comments
- minor contribution ?
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no | no |
- Primary specie
- H2 16O
- Temperature
- 10.0 ± 10.0 K
Temperature
- Method #1
- spectrum fit
- Fit function
- Gaussian
- Overlap
- moderately blended
- Peak
- 6021 ± 1 cm-1 (peak)
- Center
- 6037 ± 1 cm-1 (fit center)
- Evaluation
- validated
- Quality
- B
- FWHM
- 87 cm-1 (fit fwhm)
- Shape
- symmetric
- Evaluation
- validated
- Method
- fit intensity
- Absorption coefficient
- 30 ± 1.5 cm-1
- Strength
- medium (m)
- Evaluation
- validated
- Quality
- C
- Temperature
- 100.0 ± 10.0 K
Temperature
- Method #1
- spectrum fit
- Fit function
- Gaussian
- Overlap
- strongly blended
- Peak
- 6048 ± 1 cm-1 (peak)
- Center
- 6059 ± 1 cm-1 (fit center)
- Evaluation
- validated
- Quality
- B
- FWHM
- 99 cm-1 (fit fwhm)
- Shape
- symmetric
- Evaluation
- validated
- Method
- fit intensity
- Absorption coefficient
- 15.3 ± 1 cm-1
- Strength
- weak (w)
- Evaluation
- validated
- Quality
- C
- Temperature
- 140.0 ± 10.0 K
Temperature
- Method #1
- spectrum fit
- Fit function
- Gaussian
- Overlap
- shoulder-tail
- Peak
- 6073 ± 1 cm-1 (peak)
- Center
- 6071 ± 1 cm-1 (fit center)
- Evaluation
- validated
- Quality
- B
- FWHM
- 106 cm-1 (fit fwhm)
- Shape
- broad shoulder
- Evaluation
- validated
- Method
- fit intensity
- Absorption coefficient
- 8.1 ± 0.5 cm-1
- Relative intensity
- 3.3e-04 ± 2.0e-05
- Strength
- weak (w)
- Evaluation
- validated
- Quality
- C
- Temperature
- 270.0 ± 10.0 K
Temperature
- Method #1
- spectrum fit
- Fit function
- Gaussian
- Overlap
- strongly blended
- Center
- 6117 ± 1 cm-1 (fit center)
- Evaluation
- validated
- Quality
- B
- FWHM
- 130 cm-1 (fit fwhm)
- Shape
- undefined
- Evaluation
- validated
- Method
- fit intensity
- Absorption coefficient
- 0.1 ± 0.1 cm-1
- Strength
- extremely weak (ew)
- Evaluation
- validated
- Quality
- E
- Publications
- Data publication experiment
- Comments
- Ockman thesis 1957