Band
Title
867.0 cm-1: ν2(B) of (CO3)2- in Barytocalcite
Band type
Type
Raman scattering
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
ν2(B) B bending sym. out-p (wagging) (CO3)2- (CO3)2- no
Characteristics summary
Peak position
(cm-1)		 Center position
(cm-1)		 Width
(cm-1)		 Shape Asymmetry factor Peak intensity
(cm-1)		 Peak intensity relative Peak strength Integrated intensity
(cm-2)		 Integrated intensity relative Integrated strength Temperature
(K)		 Pressure
(bar)
867 ± 1 - 3.3 symmetric 0.0045 vvw 295.0 1
Band assignment #1
Assignment
Label
ν2(B)
Symmetry
B
Category
fundamental vibration

Evaluation

Level
fully assigned
Evaluation
undefined
# Multiplicity type Degeneracy Other band
1 no
Primary specie
(CO3)2-

Vibration modes

Label (type)
ν2 (bending sym. out-p (wagging))       Bond: (CO3)2-
Comments
O-C-O out-of-plane deformation
Texture
single crystals and powders

Temperature

Temperature
295.0 ± 5.0 K

Pressure

Pressure
1 bar
Method #1
spectrum measurement
Overlap
strongly blended
Peak
867 ± 1 cm-1 (estimated)
Evaluation
undefined
Quality
B
FWHM
3.3 cm-1 (fit fwhm)
Shape
symmetric
Evaluation
undefined
Quality
undefined
Method
baseline corrected peak intensity
Relative intensity
0.0045 ± 0.0015
Strength
very very weak (vvw)
Evaluation
undefined
Quality
E
Publication
External spectrum