Band
Title
3050.0 cm-1: 2ν2 of 12CH4 in CH4 - phase I
Type
Raman scattering
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
2 deformation 12CH4 CH4 12C-1H mode degeneracy triple
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
3050 ± 2 - 10 ± 2 symmetric m m 77.0
Label
2
Category
overtone vibration

Evaluation

Level
fully assigned
Evaluation
validated
# Multiplicity type Degeneracy Other band
1 mode degeneracy triple

Vibration modes

Label (type)
2 (deformation)       Bond: 12C-1H
Texture
crystal

Temperature

Temperature
77.0 ± 1.0 K
Formation temperature
90.7 K
Temperature max
90.7 K
Sample orientation mode
unoriented
Polarization orientation mode
depolarized
Comments
Hg lines
Method #1
spectrum measurement
Method #2
spectrum measurement
Overlap
isolated
Peak
3050 ± 2 cm-1 (peak)
Evaluation
validated
Quality
B
FWHM
10 ± 2 cm-1 (fwhm)
Shape
symmetric
Evaluation
undefined
Quality
D
Method
extrapolated
Strength
medium (m)
Evaluation
validated
Quality
undefined
Method
extrapolated
Strength
medium (m)
Quality
undefined