Band
Title
1105.0 cm-1: ν1 (A1g) of (CO3)2- in Eitelite
Type
Raman scattering
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
ν1 (A1g) A1g stretching sym. (CO3)2- CO-2/3 no
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
1105 ± 0.5 - 2.8 ± 0.3 symmetric 1 vs 295.0 1
Label
ν1 (A1g)
Symmetry
A1g
Category
fundamental vibration

Evaluation

Level
fully assigned
Evaluation
validated
# Multiplicity type Degeneracy Other band
1 no

Vibration modes

Label (type)
ν1 (stretching sym.)       Bond: CO-2/3
Comments
C-O symmetric stretch
Composition
Na2Mg(CO3)2
Texture
crystal

Temperature

Temperature
295.0 ± 5.0 K

Pressure

Pressure
1 bar
Laser wavelength
532.0 nm
Sample orientation mode
unoriented
Method #1
various
Overlap
slightly blended
Peak
1105 ± 0.5 cm-1 (various)
Evaluation
validated
Quality
A
Comments
shifted to 1102 cm-1 with 7% Ca
FWHM
2.8 ± 0.3 cm-1 (fwhm)
Shape
symmetric
Evaluation
undefined
Quality
B
Method
peak intensity
Relative intensity
1
Strength
very strong (vs)
Evaluation
undefined
Quality
undefined