- Type
- Raman scattering
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| νLT (Ag) | Ag | translation |
(CO3)2- Ca2+ |
no |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 329 ± 4 | - | 20 ± 4 | broad shoulder | 0.011 | vw | 295.0 | 1 |
- Label
- νLT (Ag)
- Symmetry
- Ag
- Category
- phonon mode
Evaluation
- Level
- fully assigned
- Evaluation
- undefined
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no |
- Label (type)
- νL (libration)
- Comments
- out-of-plane libration
- Label (type)
- νT (translation)
- Comments
- Ca2+ translation
Rotation modes
Phonon modes
- Texture
- single crystals and powders
- Temperature
- 295.0 ± 5.0 K
Temperature
- Pressure
- 1 bar
Pressure
- Laser wavelength
- 514.5 nm
- Sample orientation mode
- unoriented
- Method #1
- various
- Overlap
- shoulder-tail
- Peak
- 329 ± 4 cm-1 (various)
- Evaluation
- validated
- Quality
- C
- FWHM
- 20 ± 4 cm-1 (various)
- Shape
- broad shoulder
- Evaluation
- undefined
- Quality
- D
- Method
- estimated
- Relative intensity
- 0.011 ± 0.007
- Strength
- very weak (vw)
- Evaluation
- undefined
- Quality
- E