Band
Title
704.0 cm-1: ν4 of (CO3)2- in K2Ca(CO3)2 - phase beta
Type
Raman scattering
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
ν4 unknown bending asym. in-p (rocking) (CO3)2- (CO3)2- unknown
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
704 ± 3 - 15 ± 3 asymmetric 0.031 w 295.0 1
Label
ν4
Symmetry
unknown
Category
fundamental vibration

Evaluation

Level
partly assigned
Evaluation
undefined
# Multiplicity type Degeneracy Other band
1 unknown

Vibration modes

Label (type)
ν4 (bending asym. in-p (rocking))       Bond: (CO3)2-
Comments
in-plane deformation of CO32-
Composition
pure beta-K2Ca(CO3)2, formed at 3GPa/975°C
Texture
crystal

Temperature

Temperature
295.0 ± 5.0 K

Pressure

Pressure
1 bar
Laser wavelength
532.0 nm
Sample orientation mode
unoriented
Method #1
spectrum measurement
Overlap
strongly blended
Peak
704 ± 3 cm-1 (peak)
Evaluation
validated
Quality
C
FWHM
15 ± 3 cm-1 (fit fwhm)
Shape
asymmetric
Evaluation
validated
Quality
D
Method
peak intensity
Relative intensity
0.031 ± 0.01
Strength
weak (w)
Evaluation
undefined
Quality
E