Band
Title
11100.0 cm-1: 2ν123 of 1H2 16O in natural H2O - phase Ih
Type
absorption
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
123 combination vibration H2 16O H2O -16O-1H
H2 16O
-16O-1H
no no
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
11100 ± 100 - 400 ± 200 0.02 ± 0.01 vvw 270.0
Label
123
Category
combination vibration

Evaluation

Level
partly assigned
Evaluation
undefined
Comments
Ockman 1957
# Multiplicity type Degeneracy Other band
1 no no

Vibration modes

Label (type)
1 (stretching sym.)       Bond: -16O-1H
ν2 (bending)       Bond: H2 16O
ν3 (stretching asym.)       Bond: -16O-1H
Comments
in-phase

Temperature

Temperature
270.0 ± 10.0 K
Method #1
spectrum measurement
Overlap
moderately blended
Peak
11100 ± 100 cm-1 (peak)
Evaluation
undefined
Quality
E
Comments
error estimated
FWHM
400 ± 200 cm-1 (estimated)
Evaluation
uncertain
Quality
E
Comments
From Fig. 6 Okman 1958
Method
estimated
Absorption coefficient
0.02 ± 0.01 cm-1
Strength
very very weak (vvw)
Evaluation
uncertain
Quality
E
Comments
From Fig. 6 Okman 1958