- Title
- 6371.0 cm-1: 2ν3 (TO) of 1H2 16O and ν1+2ν2 of 1H2 16O and 2ν2+ν3 of 1H2 16O and ν1+ν1 of 1H2 16O and ν1+ν3 of 1H2 16O in natural H2O - phase Ih
- Type
- absorption
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| 2ν3 (TO) | stretching asym. | H2 16O | H2O | -16O-1H | no | no | unknown | ||
| ν1+2ν2 | combination vibration | H2 16O | H2O |
-16O-1H H2 16O |
no | no | unknown | ||
| 2ν2+ν3 | combination vibration | H2 16O | H2O |
H2 16O -16O-1H |
no | no | unknown | ||
| ν1+ν1 | combination vibration | H2 16O | H2O |
-16O-1H -16O-1H |
no | no | unknown | ||
| ν1+ν3 | combination vibration | H2 16O | H2O |
-16O-1H -16O-1H |
no | no | unknown |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 6371 ± 20 | 115 | broad shoulder | 13 ± 1 | w | 10.0 |
- Label
- ν1+2ν2
- Category
- combination vibration
Evaluation
- Level
- uncertain assignment
- Evaluation
- uncertain
- Comments
- Ockman 1957
- Contribution level
- unknown
- Contribution comments
- minor contribution ?
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no | no |
- Primary specie
- H2 16O
- Label
- 2ν2+ν3
- Category
- combination vibration
Evaluation
- Level
- uncertain assignment
- Evaluation
- uncertain
- Comments
- Ockman 1957
- Contribution level
- unknown
- Contribution comments
- minor contribution ?
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no | no |
- Primary specie
- H2 16O
- Label
- ν1+ν1
- Category
- combination vibration
Evaluation
- Level
- uncertain assignment
- Evaluation
- uncertain
- Comments
- Ockman 1957
- Contribution level
- unknown
- Contribution comments
- minor contribution ?
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no | no |
- Primary specie
- H2 16O
- Label
- ν1+ν3
- Category
- combination vibration
Evaluation
- Level
- uncertain assignment
- Evaluation
- uncertain
- Contribution level
- unknown
- Contribution comments
- minor contribution ?
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no | no |
- Primary specie
- H2 16O
- Temperature
- 10.0 ± 10.0 K
Temperature
- Method #1
- spectrum fit
- Fit function
- Gaussian
- Overlap
- shoulder-tail
- Center
- 6371 ± 20 cm-1 (fit center)
- Evaluation
- validated
- Quality
- E
- FWHM
- 115 cm-1 (fit fwhm)
- Shape
- broad shoulder
- Evaluation
- validated
- Method
- fit intensity
- Absorption coefficient
- 13 ± 1 cm-1
- Strength
- weak (w)
- Evaluation
- validated
- Quality
- C
- Publication
- Data publication experiment