- Type
- Raman scattering
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| ν2(E) | E | bending sym. out-p (wagging) | (CO3)2- | (CO3)2- | mode degeneracy | double |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 878 ± 1.5 | - | 2.8 | symmetric | 0.063 | m | 295.0 | 1 |
- Label
- ν2(E)
- Symmetry
- E
- Category
- fundamental vibration
Evaluation
- Level
- fully assigned
- Evaluation
- undefined
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | mode degeneracy | double |
- Primary specie
- (CO3)2-
- Label (type)
- ν2 (bending sym. out-p (wagging)) Bond: (CO3)2-
- Comments
- O-C-O out-of-plane deformation
Vibration modes
- Texture
- single crystals and powders
- Temperature
- 295.0 ± 5.0 K
Temperature
- Pressure
- 1 bar
Pressure
- Method #1
- spectrum measurement
- Overlap
- isolated
- Peak
- 878 ± 1.5 cm-1 (estimated)
- Evaluation
- undefined
- Quality
- B
- FWHM
- 2.8 cm-1 (estimated)
- Shape
- symmetric
- Evaluation
- undefined
- Quality
- undefined
- Method
- calculated
- Relative intensity
- 0.063
- Strength
- medium (m)
- Evaluation
- undefined
- Quality
- undefined
- Comments
- from fig. 4.35 Hollet(2020) relative to 855 cm-1