- Type
- Raman scattering
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| νL (Tg)⁻ | Tg | libration | 14N2 | N2 | mode degeneracy | triple |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 36.5 ± 1 | - | 1.5 ± 0.5 | symmetric | 0.45 | vs | 0.28 | vs | 11.0 |
- Label
- νL (Tg)⁻
- Symmetry
- Tg
- Category
- rotation
Evaluation
- Level
- fully assigned
- Evaluation
- validated
- Comments
- νLxy
- Contribution comments
- brocken mode degeneracy
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | mode degeneracy | triple |
- Primary specie
- 14N2
- Label (type)
- νL (libration)
- Comments
- Tg⁻
Rotation modes
- Texture
- crystal and film
- Temperature
- 11.0 ± 7.0 K
Temperature
- Laser wavelength
- 514.5 nm
- Sample orientation mode
- unoriented
- Polarization orientation mode
- unknown
- Method #1
- spectrum measurement
- Overlap
- moderately blended
- Peak
- 36.5 ± 1 cm-1 (peak)
- Evaluation
- validated
- Quality
- B
- FWHM
- 1.5 ± 0.5 cm-1 (fwhm)
- Shape
- symmetric
- Evaluation
- validated
- Quality
- B
- Method
- peak intensity
- Relative intensity
- 0.45
- Strength
- very strong (vs)
- Evaluation
- validated
- Quality
- undefined
- Method
- band integrated intensity
- Relative intensity
- 0.28
- Strength
- very strong (vs)
- Quality
- undefined