Band
Title
82.0 cm-1: νL,T + νL,T of 14N2 in N2 - phase alpha
Type
Raman scattering
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
νL,T + νL,T combination 14N2 N2 unknown unknown
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
82 ± 3 34 ± 5 symmetric 0.01 m 0.21 vs 18.0
Label
νL,T + νL,T
Category
combination

Evaluation

Level
partly assigned
Evaluation
validated
# Multiplicity type Degeneracy Other band
1 unknown unknown

Rotation modes

Label (type)
νL (libration)

Phonon modes

Label (type)
νT (translation)
Comments
Eg
Texture
crystal and film

Temperature

Temperature
18.0 ± 3.0 K
Laser wavelength
514.5 nm
Sample orientation mode
unoriented
Polarization orientation mode
unknown
Method #1
spectrum measurement
Overlap
moderately blended
Center
82 ± 3 cm-1 (half-max center)
Evaluation
validated
Quality
C
FWHM
34 ± 5 cm-1 (fwhm)
Shape
symmetric
Evaluation
validated
Quality
E
Comments
shape with structure
Method
peak intensity
Relative intensity
0.01
Strength
medium (m)
Evaluation
validated
Quality
undefined
Method
band integrated intensity
Relative intensity
0.21
Strength
very strong (vs)
Quality
undefined