Constituent
Name
Na-exchanged montmorillonite SWy-2 size-fraction <0.1 µm
IMA name
Montmorillonite
Class
silicate mineral
Compound type
phyllosilicate
Comments
Montmorillonite has a typical hydration number of 10 - Chemical composition and molecular mass are per half unit cell
Formula
Na0.36(Al1.53Mg0.24Fe0.23)(Si3.88Al0.12)O10(OH)2
Chemical formula
(Na,Ca)0.3(Al,Mg)2Si4O10(OH)2•n(H2O)
Elemental formula
(Na)0.36-0.3 (Al)1.65-2 (Mg)0.24-2 Fe0.23 (Si)3.88-4 O12 H2
Isotope mixture type
terrestrial abundance
  Formula Name Family Number min-max Isotope mole fraction State Relevance
Na Sodium element 0.36 - 0.3 1.0 constituent element main
Al Aluminium element 1.65 - 2 1.0 constituent element main
Mg Magnesium element 0.24 - 2 1.0 constituent element main
Fe Iron element 0.23 1.0 constituent element main
Si Silicon element 3.88 - 4 1.0 constituent element main
O Oxygen element 12 1.0 constituent element main
H Hydrogen element 2 1.0 constituent element main
Composition comments
Typical formula: (Na0.2Ca0.1)Al2.Si4O10(OH)2(H2O)10 - Common impurities: Fe, K - Intermolecular water was not taken into account in atomic composition calculation
Chemical functions
  Function Number
(OH) 2
Chemical bonds
  Bond Number
OH 1
Oxides
Formula SiO2 Al2O3 MgO Fe2O3 Na2O H2O
Mass fraction (%) 62.26 22.46 2.58 4.9 2.98 4.47

Strunz

Class
silicates (09)
Division
phyllosilicate (09.E)
Family
with mica sheets, composed of tetrahedral and octahedral nets (09.EC)
Code
09.EC.40

Dana

Major class
silicates (VIII)
Class
phyllosilicate sheets of six-membered rings (71)
Type
with 2:1 clays (71.03)
Group
Smectite group (Dioctahedral Smectites) (71.03.01a)
Code
71.03.01a.02
Phase type
crystalline
Crystal system
monoclinic
Crystal class
prismatic
Crystal class symbol
2/m (C2h)
Crystal spacegroup
C2/m
Texture
cryptocrystalline
Molar mass
374.0 g/mol
Density
N/A g/cm3
Refringence type
biaxial
Refringence sign
negative
Birefringence
0.015 - 0.020
Refraction index nα
1.485 - 1.535
Refraction index nβ
1.504 - 1.550
Refraction index nγ
1.505 - 1.550
Dispersion V
0
Color
gray white, yellow, brownish yellow, greenish yellow
Diaphaneity
translucent to opaque
Luster
N/A