Constituent
- Name
- Na-Montmorillonite
- IMA name
- Montmorillonite-Beidellite-Nontronite series
- Class
- silicate mineral
- Compound type
- phyllosilicate
- Formula
- $(Na_{0.07}Ca_{0.26}K_{0.005})[Al_{1.615}Fe^{3+}_{0.21}Mg_{0.28}Ti_{<0.01}][(Si_{3.945}Al_{0.055}]O_{10}(OH)_2$
- Chemical formula
- [(Na)1-x(Ca)0.5(1+x)]0.3[(Al)x(Mg)y(Fe3+)1-x-y]2[(Si)x(Al)1-x]4O10(OH)2•n(H2O)
- Elemental formula
- (Na)0.07-0.3 (Ca)0.26-0.15 (Al)1.67-2.5 (Fe3+)0.21-2 (Mg)0.28-0.35 (Si)3.945-4 O12 H2
- Isotope mixture type
- terrestrial abundance
- Composition comments
- perfect solid solution - Common impurities: Ti, K - This composition is for the whole dry matter, not just the smectite fraction. From Mermut & Cano 2001. Thermal analysis DTA: endotherms at 185°C (shoulder at 235°C), desorption of water: 755°C, dehydroxylation; shoulder at 810°C, exotherms at 980°C. TG: Loss in dehydroxylation range: 5.53% (theory: 5%)
- Oxides
-
Formula $SiO_{2}$ $Na_{2}O$ $CaO$ $K_{2}O$ $Al_{2}O_{3}$ $Fe_{2}O_{3}$ $MgO$ $TiO_{2}$ $P_{2}O_{5}$ Mass fraction (%) 61.46 1.47 1.18 0.2 22.05 4.37 2.94 0.09 0.003 - Oxides comments
- From Mermut & Cano 2001. Loss on heating: -550°C: 0.61-1.59%; 550-1000°C: 4.47-5.15%
Strunz
- Class
- silicates (09)
- Division
- phyllosilicate (09.E)
- Family
- with mica sheets, composed of tetrahedral and octahedral nets (09.EC)
- Code
- 09.EC.40
Dana
- Major class
- silicates (VIII)
- Class
- phyllosilicate sheets of six-membered rings (71)
- Type
- with 2:1 clays (71.03)
- Group
- Smectite group (Dioctahedral Smectites) (71.03.01a)
- Phase type
- crystalline
- Crystal system
- monoclinic
- Crystal class
- prismatic
- Crystal class symbol
- 2/m (C2h)
- Crystal spacegroup
- C2/m
- Texture
- cryptocrystalline
- Molar mass
- 389.27 - 549.07 $g/mol$
- Density
- 2.0 - 2.7 $g/cm^3$
- Refringence type
- biaxial
- Refringence sign
- negative
- Birefringence
- 0.015 - 0.035
- Refraction index $n_{\alpha}$
- 1.485 - 1.58
- Refraction index $n_{\beta}$
- 1.504 - 1.612
- Refraction index $n_{\gamma}$
- 1.505 - 1.615
- Color
- gray-green
- Diaphaneity
- translucent to opaque
- Luster
- earthy