Publication
Reference
Khanna R.~K., Zhao Guizhi, Ospina M.~J., Pearl J.~C. (1988). Crystalline sulfur dioxide: Crystal field splittings, absolute band intensities, and complex refractive indices derived from infra-red spectra. Spectrochim. Acta, Part A, 44, 581 - 586.
Names
  • R.~K. Khanna
  • Guizhi Zhao
  • M.~J. Ospina
  • J.~C. Pearl
Article and keywords
Title
Crystalline sulfur dioxide: Crystal field splittings, absolute band intensities, and complex refractive indices derived from infra-red spectra
Abstract
The infra-red absorption spectra of thin crystalline films of sulfur dioxide at 90 K are reported in the 2700-450 cm−1 region. The observed multiplicity of the bands in the regions of fundamental modes is attributed to crystal field effects, including factor group and LO\textemdashTO splittings, and naturally present minor 34S, 36S and 18O substituted isotopic species. Complex refractive indices determined by an iterative Kramers\textemdashKronig analysis of the extinction data, and absolute band strengths derived from them, are also reported in this region.
Keywords
spectroscopy, transmission spectra, optical constants spectra, band position, band vibration mode, molecular solid, SO2
Content
spectral data, band list data, experimental physics
Year
1988
Journal
Spectrochimica Acta, Part A
Volume
44
Number
6
Pages
581 - 586
Document type
article
Publication state
published
Doi
10.1016/0584-8539(88)80111-9
Identifiers