Publication
Reference
Lucazeau Guy, Novak Alexandre (1973). Low temperature Raman spectra of KHCO3 single crystal. J. Raman Spectrosc., 1, 573 - 586.
Names
  • Guy Lucazeau
  • Alexandre Novak
Article and keywords
Title
Low temperature Raman spectra of KHCO3 single crystal
Abstract
The KHCO$_3$ single crystal Raman spectra at 300K and 30K have been investigated in the 4000-5 cm-l range. The far infrared spectrum (300-60 cm-l) of polycrystalline KHCO$_3$ has also been obtained. Fifteen Raman and five infrared active lattice modes from respectively eighteen and fifteen expected ones have been observed. An assignment in terms of factor group symmetry species, rotational, translational and hydrogen bond vibrations is given. Hydrogen bond strength, OH stretching band shape and structure are discussed; combination bands involving mostly OH bending fundamentals are believed to be responsible for the main subband features.
Keywords
spectroscopy, Raman spectroscopy, Infrared spectroscopy, absorption, FIR, MIR, low temperature, band position, band width, band intensity, band attribution, minerals, carbonate, Kalicinite, KHCO3, KDCO3
Content
band list data, spectral data, experimental physics
Year
1973
Journal
Journal of Raman Spectroscopy
Volume
1
Number
6
Pages
573 - 586
Pages number
14
Document type
article
Publication state
published
Doi
10.1002/jrs.1250010607
Identifiers