Band
Title
1018.3 cm-1: ν8 of 12C1H316O1H in natural CH3OH - phase alpha
Band type
Type
absorption
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
ν8 A' stretching 12CH316OH CH3OH ≥ 12C-16O- no
Characteristics summary
Peak position
(cm-1)		 Center position
(cm-1)		 Width
(cm-1)		 Shape Asymmetry factor Peak intensity
(cm-1)		 Peak intensity relative Peak strength Integrated intensity
(cm-2)		 Integrated intensity relative Integrated strength Temperature
(K)		 Pressure
(bar)
1018.3 ± 0.2 - 10 ± 0.2 undefined 1 vs 35.0
1021 ± 1.5 - 11.5 ± 0.2 symmetric 1 vs 120.0
Band assignment #1
Assignment
Label
ν8
Symmetry
A'
Category
fundamental vibration
Method
comparison with gas phase

Evaluation

Level
fully assigned
Evaluation
validated
# Multiplicity type Degeneracy Other band
1 no
Primary specie
12CH316OH

Vibration modes

Label (type)
ν8 (stretching)       Bond: ≥ 12C-16O-

Temperature

Temperature
35.0 ± 5.0 K
Method #1
spectrum measurement: direct measurement on the absorbance spectrum, manual linear baseline for peak intensity and FWHM
Overlap
strongly blended
Peak
1018.3 ± 0.2 cm-1 (peak)
Evaluation
validated
Quality
A
FWHM
10 ± 0.2 cm-1 (fwhm)
Shape
undefined
Evaluation
validated
Quality
A
Method
peak intensity
Relative intensity
1 ± 0.01
Strength
very strong (vs)
Evaluation
undefined
Quality
A

Temperature

Temperature
120.0 ± 10.0 K
Method #1
spectrum measurement: direct measurement on the absorbance spectrum, manual linear baseline for peak intensity and FWHM
Overlap
isolated
Peak
1021 ± 1.5 cm-1 (peak)
Evaluation
validated
Quality
B
FWHM
11.5 ± 0.2 cm-1 (fwhm)
Shape
symmetric
Evaluation
validated
Quality
A
Method
peak intensity
Relative intensity
1 ± 0.01
Strength
very strong (vs)
Evaluation
undefined
Quality
A
Publications
Data publication experiment