Band
Title
1816.5 cm-1: ν23 of 32S16O18O in SO2 - phase I
Type
absorption
Comments
modif v2
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
ν23 unknown combination vibration 32S16O18O SO2 16O=32S=18O
=32S=18O
no no
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
1816.5 ± 0.2 - - unknown ew 90.0
Label
ν23
Symmetry
unknown
Category
combination vibration

Evaluation

Level
fully assigned
Evaluation
undefined
# Multiplicity type Degeneracy Other band
1 no no

Vibration modes

Label (type)
ν2 (bending)       Bond: 16O=32S=18O
ν3 (stretching asym.)       Bond: =32S=18O

Temperature

Temperature
90.0 ± 15.0 K
Comments
condensed above 77K or annealed above 160K
Method #1
spectrum measurement
Overlap
isolated
Peak
1816.5 ± 0.2 cm-1 (peak)
Evaluation
undefined
Quality
A
Shape
unknown
Evaluation
undefined
Quality
undefined
Method
estimated
Strength
extremely weak (ew)
Evaluation
undefined
Quality
undefined