Band
Title
532.0 cm-1: ν2 (A1(LO)) of 32S16O2 in SO2 - phase I
Type
absorption
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
ν2 (A1(LO)) A1 bending 32S16O2 SO2 16O=32S=16O no no
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
546 ± 2 - - unknown s 20.0
532 ± 2 - - broad shoulder s 90.0
Label
ν2 (A1(LO))
Symmetry
A1
Category
fundamental vibration

Evaluation

Level
fully assigned
Evaluation
validated
# Multiplicity type Degeneracy Other band
1 no no

Vibration modes

Label (type)
ν2 (bending)       Bond: 16O=32S=16O

Temperature

Temperature
20.0 ± 5.0 K
Comments
condensed above 77K or annealed above 160K
Method #1
spectrum measurement
Overlap
shoulder-tail
Peak
546 ± 2 cm-1 (estimated)
Evaluation
undefined
Quality
B
Shape
unknown
Evaluation
undefined
Quality
undefined
Method
extrapolated
Strength
strong (s)
Evaluation
undefined
Quality
undefined

Temperature

Temperature
90.0 ± 15.0 K
Comments
condensed above 77K or annealed above 160K
Method #1
spectrum measurement
Overlap
shoulder-tail
Peak
532 ± 2 cm-1 (estimated)
Evaluation
undefined
Quality
B
Shape
broad shoulder
Evaluation
undefined
Quality
undefined
Method
extrapolated
Strength
strong (s)
Evaluation
undefined
Quality
undefined