Matter
Name
Tholins LATMOS 95%-N2:5%-CH4:500ppm-CO
Family
carbonaceous
Level
local matter
Origins
laboratory
Provider
LATMOS
Local reference code
N2:CH4:CO=95%:5%:500ppm tholins
Preparation
raw
Method
Tholins formation by plasma discharge in a 95%-N2:5%-CH4:500ppm-CO gas mixture
Phase type
solid
Component type (group)
synthesized carbonaceous matter (plasma product)
Texture
pulverulent
Type of porosity
open pores
Texture
compact
Grain sizes
Grains Size min Size max Size median Size width Size mass fraction Grain shape
#1 110.0 $nm$ 150.0 $nm$ 0.039 spherical
#2 150.0 $nm$ 170.0 $nm$ 0.07 spherical
#3 170.0 $nm$ 190.0 $nm$ 0.122 spherical
#4 190.0 $nm$ 200.0 $nm$ 0.139 spherical
#5 200.0 $nm$ 210.0 $nm$ 0.147 spherical
#6 210.0 $nm$ 220.0 $nm$ 0.116 spherical
#7 220.0 $nm$ 230.0 $nm$ 0.147 spherical
#8 230.0 $nm$ 240.0 $nm$ 0.069 spherical
#9 240.0 $nm$ 260.0 $nm$ 0.084 spherical
#10 260.0 $nm$ 280.0 $nm$ 0.035 spherical
#11 280.0 $nm$ 320.0 $nm$ 0.022 spherical
#12 320.0 $nm$ 370.0 $nm$ 0.008 spherical
Size distribution
provided in Figure 5a of Fayole et al. 2021
Size method
grain size distribution of estimated by measuring the apparent diameter of tholins particles, averaged over 200 particles using SEM images
Atom $C$ $H$ $O$ $N$ H/C O/C N/C S/C
Mole fraction
Mass fraction 0.49 0.048 0.017 0.36
Comments
Co-polymeric insaturated structure rich in oxygen and nitrogen.
Number
1
Mode of mixing
single material
Materials
  Name Arrangement Mass (g) Mass fraction Abundance comments
Tholins granular 95%-N2:5%-CH4:500ppm-CO 1.0
Title
Tholins formation by plasma discharge in a 95%-N2:5%-CH4:500ppm-CO gas mixture

Produced matter

Matter
Tholins LATMOS 95%-N2:5%-CH4:500ppm-CO (this matter)
Processing steps
Step Date Type Process Changes
#1 2018-03-16 pressure Pumping the heated chamber down to $1.5 10^{-6}$ mbar
#2 2018-03-16 fluid physical Injection in the PAMPRE chamber of 55 sccm of $N_2:CH_4:CO$ gas in a 95%:5%:500ppm ratio (using pure N2, N2:CH4 = 90%:10% and N2:CO = 99.5%:5000ppm gas bottles (Air Liquide) with impurities limits: H2O < 3 ppm, O2 < 2 ppm et CxHy < 0.5 ppm), resulting in a pressure of $0.9 \pm 0.1$ mbar
#3 2018-03-16 irradiation irradiation using a RF CCP Plasma at 13.56 MHz and 30 W injected power of the $N_2$:$CH_4$:$CO$=95%:5%:500ppm gas mixture at ambient temperature and 0.9 mbar formation of tholins grains
#4 2018-03-20 no Collecting tholins grains from the reactor (and thus exposing them to ambient air) No changes observed macroscopically