- Type
- Raman scattering
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| δ OCO (Bg) | Bg |
bending sym. in-p (scissoring) stretching |
(HCO3)- |
-O-(-)C(-)-O- -O-H |
no |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 658.5 ± 1 | - | - | undefined | 0.05 | w | 295.0 | 1 |
- Label
- δ OCO (Bg)
- Symmetry
- Bg
- Category
- fundamental vibration
Evaluation
- Level
- fully assigned
- Evaluation
- undefined
- Comments
- From WURM database
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no |
- Primary specie
- (HCO3)-
- Label (type)
- δ O-C-O (bending sym. in-p (scissoring)) Bond: -O-(-)C(-)-O-
- ν O-H (stretching) Bond: -O-H
- Comments
- O-C-O symmetric in-plane bending + O-H stretching
Vibration modes
- Texture
- crystal
- Temperature
- 295.0 ± 5.0 K
Temperature
- Pressure
- 1 bar
Pressure
- Laser wavelength
- 532.0 nm
- Sample orientation mode
- unoriented
- Method #1
- various
- Overlap
- slightly blended
- Peak
- 658.5 ± 1 cm-1 (various)
- Evaluation
- undefined
- Quality
- B
- Shape
- undefined
- Evaluation
- undefined
- Quality
- undefined
- Method
- baseline corrected peak intensity
- Relative intensity
- 0.05 ± 0.015
- Strength
- weak (w)
- Evaluation
- undefined
- Quality
- E
- Publication
- External spectrum