- Type
- Raman scattering
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| ν 13CO3 + γ 13COH (Bg) | Bg |
stretching sym. bending out-p |
(H13C16O3)- |
(H13C16O3)- ⋝ 13C-16O-H |
unknown |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 990.5 ± 1 | - | - | undefined | 0.013 | vw | 295.0 | 1 |
- Label
- ν 13CO3 + γ 13COH (Bg)
- Symmetry
- Bg
- Category
- fundamental vibration
Evaluation
- Level
- fully assigned
- Evaluation
- undefined
- Comments
- from SSHADE: attributed to γ CO-H…O by Rudolph et al. (2006) for Kalicinite
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | unknown |
- Primary specie
- (H13C16O3)-
- Label (type)
- ν 13C-O3 (stretching sym.) Bond: (H13C16O3)-
- γ 13C-O-H (bending out-p) Bond: ⋝ 13C-16O-H
- Comments
- deformation: 13C-O3⁻ symmetric stretching + 13C-O-H out-of-plane bending
Vibration modes
- Texture
- crystal
- Temperature
- 295.0 ± 5.0 K
Temperature
- Pressure
- 1 bar
Pressure
- Laser wavelength
- 532.0 nm
- Sample orientation mode
- unoriented
- Method #1
- various
- Overlap
- slightly blended
- Peak
- 990.5 ± 1 cm-1 (various)
- Evaluation
- undefined
- Quality
- B
- Shape
- undefined
- Evaluation
- undefined
- Quality
- undefined
- Method
- baseline corrected peak intensity
- Relative intensity
- 0.013 ± 0.005
- Strength
- very weak (vw)
- Evaluation
- undefined
- Quality
- E
- Publication
- External spectrum