Band
Title
698.0 cm-1: δ OCO (Bg) of (HCO3)- in Nahcolite
Type
Raman scattering
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
δ OCO (Bg) Bg bending asym. in-p (rocking) (HCO3)- O=C(-)-O- no
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
698 ± 0.5 - - undefined 0.025 w 295.0 1
Label
δ OCO (Bg)
Symmetry
Bg
Category
fundamental vibration

Evaluation

Level
fully assigned
Evaluation
undefined
Comments
From WURM database
# Multiplicity type Degeneracy Other band
1 no

Vibration modes

Label (type)
δ O=C-O (bending asym. in-p (rocking))       Bond: O=C(-)-O-
Comments
O=C-O asymmetric in-plane bending
Texture
crystal

Temperature

Temperature
295.0 ± 5.0 K

Pressure

Pressure
1 bar
Laser wavelength
532.0 nm
Sample orientation mode
unoriented
Method #1
various
Overlap
strongly blended
Peak
698 ± 0.5 cm-1 (various)
Evaluation
undefined
Quality
A
Shape
undefined
Evaluation
undefined
Quality
undefined
Method
baseline corrected peak intensity
Relative intensity
0.025 ± 0.005
Strength
weak (w)
Evaluation
undefined
Quality
D