Bandlist 110 110

Absorption band list of SO2 in solid SO2 (phase I)

Title
Absorption band list of SO2 in solid SO2 (phase I)
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Data
Individual bands
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Representation
Simple
Gaussian
Peaks
Data
Unit:  Range: Valid spectral range(s): 500.0 - 5050.0 cm-1
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Band list reference
Schmitt, Bernard and The SSHADE Band List Committee (2021): Absorption band list of SO2 in solid SO2 (phase I). Version 2. SSHADE (OSUG Data Center). Dataset/Band list Data. https://doi.org/10.26302/SSHADE/BANDLIST_ABS_SO2_SO2-I
Publication(s)
Type
absorption
Description
FIR-MIR-NIR absorption band list of SO2 in solid SO2 (phase I) at 20, 90 and 125 K
Number of bands
110
Comments
the compilation at the different temperatures did not cover the same spectral range, due to data availability
Parent spectra
Constituent and primary specie
Constituent
SO2 - phase I
Primary specie
SO2 (Sulfur dioxide)
Bands
Position (cm-1) Width (cm-1) Peak intensity (cm-1) Relative intensity Strength Transition mode Mode type(s) Bond Specie(s) Degeneracy Resonances
67 ± 1 67 ± 1 unknown
νTy (B1)
translation
32S16O2
no
80 ± 1 80 ± 1 unknown
νLy (B1)
libration
32S16O2
no
86 ± 2 86 ± 2 unknown
νLy (B2)
libration
32S16O2
no
102.5 ± 1 102.5 ± 1 unknown
νTx (B2)
translation
32S16O2
no
138 ± 1 138 ± 1 unknown
νLx (B2)
libration
32S16O2
no
159 ± 3 159 ± 3 unknown
νLx (B1)
libration
32S16O2
no
514 ± 0.3 514 ± 0.3 m
impurity ?
34S16O2
no
517 ± 0.5 517 ± 0.5 1.3 ± 0.3 0.015 m
ν2
bending
16O=32S=18O
32S16O18O
no
521.5 ± 0.5 521.5 ± 0.5 2.2 ± 0.2 0.46 vs
ν2 (A1(TO))
bending
16O=32S=16O
32S16O2
no
522.5 ± 0.3 522.5 ± 0.3 s
ν2 (A2?)
bending
16O=32S=16O
32S16O2
no
532 ± 2 532 ± 2 s
ν2 (A1(LO))
bending
16O=32S=16O
32S16O2
no
586 ± 1.5 586 ± 1.5 ew
ν2+νLy
bending
libration
16O=32S=16O
32S16O2
no
607 ± 2 607 ± 2 ew
ν2+νLy
bending
libration
16O=32S=16O
32S16O2
no
621 ± 1.5 621 ± 1.5 ew
ν2+νLy
bending
libration
16O=32S=16O
32S16O2
no
659 ± 1.5 659 ± 1.5 ew
ν2+νLy
bending
libration
16O=32S=16O
32S16O2
no
1099 ± 0.3 1099 ± 0.3 vvw
ν1
stretching sym.
=32S=18O
32S18O2
no
1112.5 ± 0.3 1112.5 ± 0.3 6.0e-04 w
ν1
stretching sym.
=34S=18O
34S16O18O
no
1120.5 ± 0.3 1120.5 ± 0.3 1.3 ± 0.1 0.018 w
ν1
stretching sym.
=32S=18O
32S16O18O
no
1134.5 ± 0.5 1134.5 ± 0.5 1.2 ± 0.3 0.005 m
ν1
stretching sym.
=32S=17O
32S16O17O
no
1140 ± 0.5 1140 ± 0.5 1.5 ± 0.1 0.425 vs
ν1
stretching sym.
=34S=16O
34S16O2
no
1143 ± 1 1143 ± 1 1.2 ± 0.7 0.78 vs
ν1 (A1(TO))
stretching sym.
=32S=16O
32S16O2
no
1149 ± 1 1149 ± 1 6 ± 2 0.4 vs
ν1 (A1(LO))
stretching sym.
=32S=16O
32S16O2
no
1196.5 ± 1 1196.5 ± 1 ew
ν1+νLy
stretching sym.
libration
=32S=16O
32S16O2
no
1206 ± 1 1206 ± 1 ew
ν1+νLy
stretching asym.
libration
=32S=16O
32S16O2
no
1227 ± 1 1227 ± 1 ew
ν1+νLy
stretching asym.
libration
=32S=16O
32S16O2
no
1244 ± 1.5 1244 ± 1.5 ew
ν1+νLy
stretching asym.
libration
=32S=16O
32S16O2
no
1280 ± 4 1280 ± 4 ew
ν1+νLy
stretching asym.
libration
=32S=16O
32S16O2
no
1281 ± 0.3 1281 ± 0.3 ew
ν3
stretching asym.
=32S=18O
32S18O2
no
1288 ± 0.5 1288 ± 0.5 0.002 ± 0.001 ew
ν3
stretching asym.
=36S=16O
36S16O2
no
1302.8 ± 0.4 1302.8 ± 0.4 vs
ν3
stretching asym.
=32S=18O
32S16O18O
no
1304.3 ± 0.3 1304.3 ± 0.3 0.63 vs
ν3
stretching asym.
=34S=16O
34S16O2
no
1310.5 ± 0.8 1310.5 ± 0.8 3.5 ± 0.7 1 vs
ν3 (B1(TO))
stretching asym.
=32S=16O
32S16O2
no
1322.5 ± 1 1322.5 ± 1 3 ± 0.5 1.01 vs
ν3 (B2(TO))
stretching asym.
=32S=16O
32S16O2
no
1328 ± 1 1328 ± 1 s
ν3
stretching asym.
=34S=16O
34S16O2
no
1341 ± 4 1341 ± 4 15 ± 4 0.5 vs
ν3 (B1(LO))
ν3 (B2(LO))
stretching asym.
stretching asym.
=32S=16O
=32S=16O
32S16O2
32S16O2
no
no

1377.5 ± 1.5 1377.5 ± 1.5 ew
ν3+νLy
stretching asym.
libration
=32S=16O
32S16O2
no
1393.5 ± 2 1393.5 ± 2 ew
ν3+νLy
stretching asym.
libration
=32S=16O
32S16O2
no
1415 ± 1.5 1415 ± 1.5 ew
ν3+νLy
stretching asym.
libration
=32S=16O
32S16O2
no
1453 ± 2 1453 ± 2 ew
ν3+νLy
stretching asym.
libration
=32S=16O
32S16O2
no
1611.3 ± 0.3 1611.3 ± 0.3 vvw
ν2
bending
-O-H
H2O
no
1816.5 ± 0.2 1816.5 ± 0.2 ew
ν2+ν3
bending
stretching asym.
16O=32S=18O
=32S=18O
32S16O18O
no
1824 ± 0.5 1824 ± 0.5 ew
ν2+ν3
bending
stretching asym.
16O=34S=16O
=34S=16O
34S16O2
no
1832.5 ± 0.5 1832.5 ± 0.5 ew
ν2+ν3
bending
stretching asym.
16O=33S=16O
=33S=16O
33S16O2
no
1850 ± 0.5 1850 ± 0.5 ew
ν2+ν3
bending
stretching asym.
16O=32S=16O
=32S=16O
32S16O2
no
2217.5 ± 0.3 2217.5 ± 0.3 2.1 ± 0.2 0.15 ± 0.03 vvw
2ν1
stretching sym.
=34S=18O
34S16O18O
no
2233.5 ± 0.3 2233.5 ± 0.3 2.1 ± 0.1 2.55 ± 0.1 w
2ν1
stretching sym.
=32S=18O
32S16O18O
no
2244.8 ± 0.3 2244.8 ± 0.3 2.5 ± 0.5 0.04 ± 0.01 vvw
2ν1
stretching sym.
=34S=17O
34S16O17O
no
2261 ± 0.3 2261 ± 0.3 2.1 ± 0.1 0.65 ± 0.05 vw
2ν1
stretching sym.
=32S=17O
32S16O17O
no
2273.8 ± 0.3 2273.8 ± 0.3 2.1 ± 0.2 10 ± 0.5 w
2ν1
stretching sym.
=34S=16O
34S16O2
no
2281 ± 0.3 2281 ± 0.3 2 ± 0.4 1.5 ± 0.3 vw
2ν1
stretching sym.
=33S=16O
33S16O2
no
2287.5 ± 0.5 2287.5 ± 0.5 4.6 ± 0.2 147 ± 10 m
2ν1
stretching sym.
=32S=16O
32S16O2
no
2301 ± 2 2301 ± 2 13 ± 3 w
2ν1+νL,T
stretching sym.
translation
libration
=32S=16O
32S16O2

2413 ± 0.3 2413 ± 0.3 2.4 ± 0.2 9 ± 1 w
ν1+ν3
stretching sym.
stretching asym.
=32S=18O
=32S=18O
32S16O18O
no
2434.5 ± 0.3 2434.5 ± 0.3 3.2 ± 0.2 75 ± 5 m
ν1+ν3
stretching sym.
stretching asym.
=34S=16O
=34S=16O
34S16O2
no
2445.3 ± 0.5 2445.3 ± 0.5 8 ± 1 w
ν1+ν3
stretching sym.
stretching asym.
=33S=16O
=33S=16O
33S16O2
no
2457 ± 0.3 2457 ± 0.3 6.3 ± 0.3 550 ± 25 s
ν1+ν3
stretching sym.
stretching asym.
=32S=16O
=32S=16O
32S16O2
no
2473 ± 2 2473 ± 2 13 ± 3 w
ν1+ν3+νL,T
stretching sym.
stretching asym.
translation
libration
=32S=16O
=32S=16O
32S16O2

2516 ± 1 2516 ± 1 3 ± 0.2 w
ν1+ν3+νL,T
stretching sym.
stretching asym.
translation
libration
=32S=16O
=32S=16O
32S16O2

2531 ± 3 2531 ± 3 3 ± 0.2 w
ν1+ν3+νL,T
stretching sym.
stretching asym.
translation
libration
=32S=16O
=32S=16O
32S16O2

2547.5 ± 1 2547.5 ± 1 3.2 ± 0.2 w
ν1+ν3+νL,T
stretching sym.
stretching asym.
translation
libration
=32S=16O
=32S=16O
32S16O2

2598.5 ± 0.3 2598.5 ± 0.3 1.4 ± 0.1 0.5 ± 0.05 vw
2ν3?
stretching asym.
=32S=18O
32S16O18O
no
2602.7 ± 0.3 2602.7 ± 0.3 1.6 ± 0.2 0.35 ± 0.05 vw
2ν3?
stretching asym.
=34S=16O
34S16O2
no
2628 ± 0.5 2628 ± 0.5 4 ± 1 0.3 ± 0.05 vw
2ν3 (B1(TO))?
stretching asym.
=32S=16O
32S16O2
no
2646.5 ± 0.3 2646.5 ± 0.3 9.9 ± 0.3 5.2 ± 0.1 w
2ν3 (B2(TO))?
stretching asym.
=32S=16O
32S16O2
no
2680 ± 10 2680 ± 10 0.6 ± 0.2 vw
2ν3+νL,T
stretching asym.
translation
libration
=32S=16O
32S16O2

2725 ± 2 2725 ± 2 0.2 ± 0.05 vw
2ν3+νL,T
stretching asym.
translation
libration
=32S=16O
32S16O2

2744 ± 0.3 2744 ± 0.3 1.2 ± 0.2 0.02 ± 0.005 vvw
2ν1+ν2
stretching sym.
bending
=32S=18O
16O=32S=18O
32S16O18O
no
2790.5 ± 0.3 2790.5 ± 0.3 1.2 ± 0.2 0.16 ± 0.01 vvw
2ν1+ν2
stretching sym.
bending
=34S=16O
16O=34S=16O
34S16O2
no
2799.3 ± 0.3 2799.3 ± 0.3 1.3 ± 0.2 0.03 ± 0.005 vvw
2ν1+ν2
stretching sym.
bending
=33S=16O
16O=33S=16O
33S16O2
no
2808.5 ± 0.3 2808.5 ± 0.3 2.4 ± 0.2 1.08 ± 0.05 vw
2ν1+ν2
stretching sym.
bending
=32S=16O
16O=32S=16O
32S16O2
no
2815 ± 5 2815 ± 5 0.1 ± 0.03 vvw
2ν1+ν2+νL,T
stretching sym.
bending
translation
libration
=32S=16O
16O=32S=16O
32S16O2

2821 ± 1 2821 ± 1 0.2 ± 0.1 vw
2ν1+ν2+νL,T
stretching sym.
bending
translation
libration
=32S=16O
16O=32S=16O
32S16O2

2950 ± 0.3 2950 ± 0.3 1.6 ± 0.2 0.024 ± 0.002 vvw
ν1+ν2+ν3
stretching sym.
bending
stretching asym.
=34S=16O
16O=34S=16O
=34S=16O
34S16O2
no
2962.5 ± 0.3 2962.5 ± 0.3 1.7 ± 0.3 0.007 ± 0.001 ew
ν1+ν2+ν3
stretching sym.
bending
stretching asym.
=33S=16O
16O=33S=16O
=33S=16O
33S16O2
no
2976 ± 0.5 2976 ± 0.5 2.2 ± 0.2 0.33 ± 0.02 vw
ν1+ν2+ν3
stretching sym.
bending
stretching asym.
=32S=16O
16O=32S=16O
=32S=16O
32S16O2
no
2987 ± 0.5 2987 ± 0.5 0.007 ± 0.002 ew
ν1+ν2+ν3+νL,T
stretching sym.
bending
stretching asym.
translation
libration
=32S=16O
16O=32S=16O
=32S=16O
32S16O2

2993 ± 0.3 2993 ± 0.3 0.015 ± 0.005 ew
ν1+ν2+ν3+νL,T
stretching sym.
bending
stretching asym.
translation
libration
=32S=16O
16O=32S=16O
=32S=16O
32S16O2

3004 ± 0.5 3004 ± 0.5 0.035 ± 0.01 vvw
ν1+ν2+ν3+νL,T
stretching sym.
bending
stretching asym.
translation
libration
=32S=16O
16O=32S=16O
=32S=16O
32S16O2

3010.5 ± 0.5 3010.5 ± 0.5 0.034 ± 0.02 vvw
ν1+ν2+ν3+νL,T
stretching sym.
bending
stretching asym.
translation
libration
=32S=16O
16O=32S=16O
=32S=16O
32S16O2

3399.8 ± 0.3 3399.8 ± 0.3 1.3 ± 0.1 0.21 ± 0.02 vw
3ν1
stretching sym.
=34S=16O
34S16O2
no
3410.5 ± 0.3 3410.5 ± 0.3 1.4 ± 0.2 0.045 ± 0.005 vvw
3ν1
stretching sym.
=33S=16O
33S16O2
no
3421.5 ± 0.3 3421.5 ± 0.3 1.8 ± 0.1 1.4 ± 0.1 vw
3ν1
stretching sym.
=32S=16O
32S16O2
no
3428.5 ± 0.3 3428.5 ± 0.3 0.065 ± 0.01 vvw
3ν1+νL,T
stretching sym.
translation
libration
=32S=16O
32S16O2

3432 ± 0.5 3432 ± 0.5 0.07 ± 0.01 vvw
3ν1+νL,T
stretching sym.
translation
libration
=32S=16O
32S16O2

3437 ± 0.3 3437 ± 0.3 0.095 ± 0.005 vvw
3ν1+νL,T
stretching sym.
translation
libration
=32S=16O
32S16O2

3440 ± 0.5 3440 ± 0.5 0.034 ± 0.02 vvw
3ν1+νL,T
stretching sym.
translation
libration
=32S=16O
32S16O2

3514 ± 0.3 3514 ± 0.3 1.6 ± 0.1 0.15 ± 0.01 vvw
2ν1+ν3
stretching sym.
stretching asym.
=32S=18O
=32S=18O
32S16O18O
no
3554 ± 0.3 3554 ± 0.3 1.6 ± 0.2 1 ± 0.05 vw
2ν1+ν3
stretching sym.
stretching asym.
=34S=16O
=34S=16O
34S16O2
no
3569 ± 0.3 3569 ± 0.3 1.8 ± 0.2 0.22 ± 0.03 vw
2ν1+ν3
stretching sym.
stretching asym.
=33S=16O
=33S=16O
33S16O2
no
3584.2 ± 0.3 3584.2 ± 0.3 1.7 ± 0.1 16 ± 0.5 w
2ν1+ν3
stretching sym.
stretching asym.
=32S=16O
=32S=16O
32S16O2
no
3593 ± 0.3 3593 ± 0.3 0.53 ± 0.1 vw
2ν1+ν3+νL,T
stretching sym.
stretching asym.
translation
libration
=32S=16O
=32S=16O
32S16O2

3600.8 ± 0.3 3600.8 ± 0.3 0.34 ± 0.05 vw
2ν1+ν3+νL,T
stretching sym.
stretching asym.
translation
libration
=32S=16O
=32S=16O
32S16O2

3605 ± 0.3 3605 ± 0.3 0.35 ± 0.05 vw
2ν1+ν3+νL,T
stretching sym.
stretching asym.
translation
libration
=32S=16O
=32S=16O
32S16O2

3615.5 ± 1 3615.5 ± 1 0.19 ± 0.05 vvw
2ν1+ν3+νL,T
stretching sym.
stretching asym.
translation
libration
=32S=16O
=32S=16O
32S16O2

3756 ± 0.3 3756 ± 0.3 1.7 ± 0.1 0.2 ± 0.02 vvw
ν1+2ν3
stretching sym.
stretching asym.
=32S=16O
=32S=16O
32S16O2
no
3761.5 ± 0.5 3761.5 ± 0.5 0.021 ± 0.005 vvw
ν1+2ν3+νL,T
stretching sym.
stretching asym.
translation
libration
=32S=16O
=32S=16O
32S16O2

3781 ± 1 3781 ± 1 0.04 ± 0.005 vvw
ν1+2ν3+νL,T
stretching sym.
stretching asym.
translation
libration
=32S=16O
=32S=16O
32S16O2

3791.5 ± 0.5 3791.5 ± 0.5 0.025 ± 0.01 vvw
ν1+2ν3+νL,T
stretching sym.
stretching asym.
translation
libration
=32S=16O
=32S=16O
32S16O2

3805 ± 1 3805 ± 1 0.005 ± 0.002 ew
ν1+2ν3+νL,T
stretching sym.
stretching asym.
translation
libration
=32S=16O
=32S=16O
32S16O2

3883 ± 0.3 3883 ± 0.3 1.6 ± 0.1 0.04 ± 0.005 vvw
3ν3
stretching asym.
=32S=18O
32S16O18O
no
3890.5 ± 0.3 3890.5 ± 0.3 1.9 ± 0.1 0.375 ± 0.02 vw
3ν3
stretching asym.
=34S=16O
34S16O2
no
3913 ± 0.3 3913 ± 0.3 1.8 ± 0.2 0.07 ± 0.01 vvw
3ν3
stretching asym.
=33S=16O
33S16O2
no
3936.3 ± 0.3 3936.3 ± 0.3 5.5 ± 0.3 2.45 ± 0.05 w
3ν3
stretching asym.
=32S=16O
32S16O2
no
3943 ± 1 3943 ± 1 0.6 ± 0.5 vw
3ν3+νL,T
stretching asym.
translation
libration
=32S=16O
32S16O2

3957.3 ± 0.3 3957.3 ± 0.3 0.25 ± 0.1 vw
3ν3+νL,T
stretching asym.
translation
libration
=32S=16O
32S16O2

4101.5 ± 0.3 4101.5 ± 0.3 1.5 ± 0.1 0.03 ± 0.003 vvw
2ν1+ν2+ν3
stretching sym.
bending
stretching asym.
=32S=16O
16O=32S=16O
=32S=16O
32S16O2
no
4547.5 ± 0.3 4547.5 ± 0.3 1.6 ± 0.2 0.014 ± 0.003 ew
4ν1
stretching sym.
=32S=16O
32S16O2
no
4704 ± 0.3 4704 ± 0.3 2.8 ± 0.2 0.19 ± 0.02 vvw
3ν1+ν3
stretching sym.
stretching asym.
=32S=16O
=32S=16O
32S16O2
no
4993 ± 0.3 4993 ± 0.3 1.3 ± 0.1 0.013 ± 0.003 ew
ν1+3ν3
stretching sym.
stretching asym.
=34S=16O
=34S=16O
34S16O2
no
5046.8 ± 0.3 5046.8 ± 0.3 2.7 ± 0.2 0.24 ± 0.02 vw
ν1+3ν3
stretching sym.
stretching asym.
=32S=16O
=32S=16O
32S16O2
no
Spectral range type(s)
FIR, MIR, NIR
Spectral range(s)
500 - 1200 cm-1, 2500 - 5050 cm-1
Reference position infrared
1324 cm-1

Versions

Release date
2024-12-25 22:43:45 UTC+0000
Version (Date)
#2 (2024-12-25 22:43:45 UTC+0000)
History
25/12/24: new version v2: added a series of 16 very weak combinations bands
Older version(s)
History
Date Mode Version Status Comments
2021-11-16 22:16:04 UTC+0000 first import #1
Analysis
Compilation and review of most published papers on SO2-I from the Far-IR to the Near-IR: Wiener and Nixon (1956), Giguere and Falk (1956), Barbe et al. (1971), Anderson and Campbell (1977), Khanna et al. (1988), Tafi et al. (1991), Schmitt et al. (1994), Nash and Netts (1995), Schriver-Mazzuoli et al. (2003) and reanalysis of the data in Schmitt et al. (1994)
Quality flag
4
Validation date
2021-11-14
Validators