Band
Title
106.5 cm-1: νLT (Ag) of (HCO3)- & K⁺ in Kalicinite
Type
Raman scattering
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
νLT (Ag) Ag translation (HCO3)-
K⁺
no
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
106.5 ± 1 - 9 ± 2 undefined 1.65 vs 295.0 1
Label
νLT (Ag)
Symmetry
Ag
Category
phonon mode

Evaluation

Level
fully assigned
Evaluation
undefined
Comments
from theoretical WURM database
# Multiplicity type Degeneracy Other band
1 no
Primary specie
(HCO3)-
Primary specie
K⁺

Rotation modes

Label (type)
νL (libration)
Comments
in-plane and out-of-plane libration

Phonon modes

Label (type)
νT (translation)
Comments
K⁺ translation
Texture
crystal

Temperature

Temperature
295.0 ± 5.0 K

Pressure

Pressure
1 bar
Method #1
various
Overlap
strongly blended
Peak
106.5 ± 1 cm-1 (various)
Evaluation
undefined
Quality
B
FWHM
9 ± 2 cm-1 (fwhm)
Shape
undefined
Evaluation
undefined
Quality
D
Method
baseline corrected peak intensity
Relative intensity
1.65 ± 1.35
Strength
very strong (vs)
Evaluation
undefined
Quality
E
Comments
vs at 780nm