Band
Title
128.0 cm-1: νT (Ag) of (HCO3)- & K⁺ in Kalicinite
Type
Raman scattering
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
νT (Ag) Ag translation (HCO3)-
K⁺
no
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
128 ± 1 - - shoulder 0.003 vvw 295.0 1
Label
νT (Ag)
Symmetry
Ag
Category
phonon mode

Evaluation

Level
fully assigned
Evaluation
undefined
Comments
from theoretical WURM database
# Multiplicity type Degeneracy Other band
1 no
Primary specie
(HCO3)-
Primary specie
K⁺

Phonon modes

Label (type)
νT (translation)
Comments
HCO3^− out-of-plane translation + K⁺ translation
Texture
crystal

Temperature

Temperature
295.0 ± 5.0 K

Pressure

Pressure
1 bar
Laser wavelength
633.0 nm
Sample orientation mode
unoriented
Method #1
various
Overlap
shoulder-tail
Peak
128 ± 1 cm-1 (fit peak)
Evaluation
undefined
Quality
B
Shape
shoulder
Evaluation
undefined
Quality
undefined
Method
baseline corrected peak intensity
Relative intensity
0.003 ± 0.0015
Strength
very very weak (vvw)
Evaluation
undefined
Quality
E