- Type
- Raman scattering
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| νLT (Bg) | Bg | translation |
(HCO3)- K⁺ |
no | |||||
| νT (Ag) | Ag | translation |
(HCO3)- K⁺ |
no |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 79.5 ± 1 | - | 4.5 ± 0.5 | unknown | 0.55 | s | 295.0 | 1 |
- Label
- νLT (Bg)
- Symmetry
- Bg
- Category
- phonon mode
Evaluation
- Level
- fully assigned
- Evaluation
- undefined
- Comments
- from theoretical WURM database
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no |
- Label (type)
- νL (libration)
- Comments
- in-plane and out-of-plane libration
- Label (type)
- νT (translation)
- Comments
- K⁺ translation
Rotation modes
Phonon modes
- Label
- νT (Ag)
- Symmetry
- Ag
- Category
- phonon mode
Evaluation
- Level
- fully assigned
- Evaluation
- undefined
- Comments
- from theoretical WURM database
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no |
- Label (type)
- νT (translation)
- Comments
- HCO3^− out-of-plane translation + K⁺ translation
Phonon modes
- Texture
- crystal
- Temperature
- 295.0 ± 5.0 K
Temperature
- Pressure
- 1 bar
Pressure
- Method #1
- various
- Overlap
- slightly blended
- Peak
- 79.5 ± 1 cm-1 (fit peak)
- Evaluation
- undefined
- Quality
- B
- FWHM
- 4.5 ± 0.5 cm-1 (fwhm)
- Shape
- unknown
- Evaluation
- undefined
- Quality
- B
- Method
- baseline corrected peak intensity
- Relative intensity
- 0.55 ± 0.25
- Strength
- strong (s)
- Evaluation
- undefined
- Quality
- E