- Title
- 214.0 cm-1: νL (Ag) of (HCO3)- and νL (Bg) of (HCO3)- and νL (Ag) of (HCO3)- in Kalicinite
- Type
- Raman scattering
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| νL (Ag) | Ag | libration | (HCO3)- | no | |||||
| νL (Bg) | Bg | libration | (HCO3)- | no | |||||
| νL (Ag) | Ag | libration | (HCO3)- | no |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 214 ± 1 | - | 17 ± 1 | high frequency tail | 0.017 | vw | 295.0 | 1 |
- Label
- νL (Ag)
- Symmetry
- Ag
- Category
- rotation
Evaluation
- Level
- fully assigned
- Evaluation
- undefined
- Comments
- from theoretical WURM database
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no |
- Primary specie
- (HCO3)-
- Label (type)
- νL (libration)
- Comments
- out-of-plane libration
Rotation modes
- Label
- νL (Bg)
- Symmetry
- Bg
- Category
- rotation
Evaluation
- Level
- fully assigned
- Evaluation
- undefined
- Comments
- from theoretical WURM database
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no |
- Primary specie
- (HCO3)-
- Label (type)
- νL (libration)
- Comments
- in-plane libration
Rotation modes
- Label
- νL (Ag)
- Symmetry
- Ag
- Category
- rotation
Evaluation
- Level
- fully assigned
- Evaluation
- undefined
- Comments
- from theoretical WURM database
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no |
- Primary specie
- (HCO3)-
- Label (type)
- νL (libration)
- Comments
- in-plane libration
Rotation modes
- Texture
- crystal
- Temperature
- 295.0 ± 5.0 K
Temperature
- Pressure
- 1 bar
Pressure
- Method #1
- various
- Overlap
- slightly blended
- Peak
- 214 ± 1 cm-1 (various)
- Evaluation
- undefined
- Quality
- B
- FWHM
- 17 ± 1 cm-1 (fwhm)
- Shape
- high frequency tail
- Evaluation
- undefined
- Quality
- C
- Method
- baseline corrected peak intensity
- Relative intensity
- 0.017 ± 0.01
- Strength
- very weak (vw)
- Evaluation
- undefined
- Quality
- E