Band
Title
113.0 cm-1: νLT (Bg) of (HCO3)- & K⁺ in Kalicinite
Type
Raman scattering
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
νLT (Bg) Bg translation (HCO3)-
K⁺
no
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
113 ± 1 - 8 ± 2 sharp shoulder 0.75 vs 295.0 1
Label
νLT (Bg)
Symmetry
Bg
Category
phonon mode

Evaluation

Level
partly assigned
Evaluation
undefined
# Multiplicity type Degeneracy Other band
1 no
Primary specie
(HCO3)-
Primary specie
K⁺

Rotation modes

Label (type)
νL (libration)
Comments
out-of-plane libration

Phonon modes

Label (type)
νT (translation)
Comments
HCO3^− in-plane translation + K⁺ translation
Texture
crystal

Temperature

Temperature
295.0 ± 5.0 K

Pressure

Pressure
1 bar
Method #1
various
Overlap
strongly blended
Peak
113 ± 1 cm-1 (various)
Evaluation
undefined
Quality
B
FWHM
8 ± 2 cm-1 (fwhm)
Shape
sharp shoulder
Evaluation
undefined
Quality
D
Method
baseline corrected peak intensity
Relative intensity
0.75 ± 0.6
Strength
very strong (vs)
Evaluation
undefined
Quality
E
Comments
vs at 780nm